The Three Valleys Community Foundation distributed nearly $4.5 million in the past year.
More than half of the total was for the Alameda County Opioid Innovative Mini-Grants.
The money came from a legal settlement with the pharmaceutical companies that manufacture fentanyl and other opioids.
The initial round of grants will go to recipients by April 1, CEO Kelly Bowers said.
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Tom’s, the social enterprise popular for its shoes, has released a pair of shoes and a pair of shades to benefit Make It Right, a nonprofit founded by Brad Pitt in 2007 that builds affordable, green homes, buildings and communities for underserved and low-income populations.